Ngwaahịa

A na-egosi mgbagwoju anya [Cp * Ru (MeCN) 3] PF6 iji mee ka hydrosilylation nke ọtụtụ alkynes dị iche iche.Terminal alkynes na-enye ohere ịnweta ngwaahịa alfa-vinylsilane nwere ezigbo regioselectivity.Ọmụmụ akara Deuterium na-egosi na usoro mgbakwunye trans dị ọcha na-arụ ọrụ.Otu mgbagwoju ahụ na-arụ ọrụ n'ime alkyne hydrosilylation, ebe a na-edobe nhọrọ zuru oke maka usoro mgbakwunye trans.Ọtụtụ klaasị mkpụrụ osisi alkyne dị n'ime, gụnyere propargylic alcohols na alfa, ogige beta-alkynyl carbonyl, na-enye ohere guzobe vinylsilane regioselective.Nkwekọrịta dị iche iche nke silanes dị ịrịba ama, gụnyere alkyl-, aryl-, alkoxy- na halosilanes.A na-egosipụta uru a na njikọ kpọmkwem nke mkpụrụ triene maka cycloadditions intramolecular diels-Alder nke nwere silicon-tethered.