Ngwaahịa

2,3,4,6-Tetrakis-O-trimethylsilyl-D-gluconolactone (TMS-D-glucose lactone) bụ ngwakọta kemịkalụ mara maka ngwa ya na njikọ organic, ọkachasị na ngalaba nke kemịkalụ carbohydrate.Ọ bụ ihe sitere na D-glucose, shuga sitere n'okike, ma nwee ihe pụrụ iche na-eme ka ọ baa uru na mmeghachi omume kemịkalụ dị iche iche. Otu n'ime isi ojiji nke TMS-D-glucose lactone bụ otu nchebe na kemịkalụ carbohydrate.Carbohydrates, gụnyere sugars, nwere ike inwe ọtụtụ hydroxyl otu, nke nwere ike imeghachi omume na ndị ọzọ reagents ma ọ bụ na-eme mgbanwe achọghị n'oge njikọ.Site n'ichekwa otu hydroxyl kpọmkwem site na iji TMS-D-glucose lactone, ndị na-ahụ maka kemịkalụ nwere ike ịchịkwa nsonaazụ mmeghachi omume ma na-emegharị usoro carbohydrate nke ọma.Mgbe mmeghachi omume achọrọ zuru oke, enwere ike iwepụ otu ndị na-echebe ngwa ngwa, na-ekpughe ngwaahịa a chọrọ.TMS-D-glucose lactone na-achọtakwa ngwa ngwa dị ka onye na-emekọrịta ihe na njikọ nke ihe ndị na-emepụta carbohydrate dị mgbagwoju anya.Site n'ịgbanwe otu hydroxyl nke TMS-D-glucose lactone, ndị na-ahụ maka kemịkalụ nwere ike iwebata ọtụtụ ọrụ dị iche iche ma ọ bụ ihe ndị ọzọ dochie anya n'ime molekul carbohydrate.Nke a na-enye ohere ịmepụta ogige carbohydrate dị iche iche nke nwere ngwa ngwa na ọgwụ, ihe ịchọ mma, na sayensị ihe. Tụkwasị na nke a, a na-eji TMS-D-glucose lactone na njikọ nke ndị na-enye onyinye glycosyl maka mmeghachi omume glycosylation.Glycosylation bụ nzọụkwụ dị mkpa n'ịmepụta njikọ glycosidic, nke dị mkpa maka ịmepụta carbohydrates na glycoconjugates.TMS-D-glucose lactone nwere ike gbanwee gaa na ndị na-enye onyinye glycosyl, nke na-eme dị ka ndị na-emeghachi omume na mmeghachi omume glycosylation, na-eme ka njikọ nke carbohydrates na ụmụ irighiri ihe ndị ọzọ. Ọzọkwa, TMS-D-glucose lactone na-arụ ọrụ na mmepụta nke polymers dabeere carbohydrate.Site na idobe TMS-D-glucose lactone na mmeghachi omume polymerization, ndị na-ahụ maka kemịkalụ nwere ike mepụta ụdọ polymer ma ọ bụ netwọkụ nwere ọkpụkpụ azụ carbohydrate.Ndị polymers carbohydrate ndị a nwere ike ịnwe ihe pụrụ iche ma nwee ike ịchọta ngwa na mpaghara dị ka usoro nnyefe ọgwụ, bioengineering, na biomaterials. Ọ dị mma ịmara na TMS-D-glucose lactone kwesịrị iji nlezianya na-edozi ya n'ihi mmiri ya na mmetụta ikuku.A na-echekwa ya ma na-edozi ya n'okpuru ikuku nitrogen ma ọ bụ argon iji gbochie mmebi. Na nchịkọta, 2,3,4,6-Tetrakis-O-trimethylsilyl-D-gluconolactone (TMS-D-glucose lactone) bụ ihe dị iche iche eji eme ihe na ya. kemịkalụ carbohydrate.Ngwa ya bụ isi gụnyere ichedo kemịkalụ otu, njikọ etiti, nhazi glycosyl na-enye onyinye, yana imepụta polymers dabere na carbohydrate.Site n'iji TMS-D-glucose lactone n'ọrụ na usoro ndị a, ndị na-ahụ maka kemịkalụ nwere ike nweta njikwa kacha mma na mmeghachi omume carbohydrate ma mepụta usoro carbohydrate dị iche iche nwere ngwa nwere ike na mpaghara dị iche iche.